Tag: M.W:200-300

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 18583-60-3, is researched, Molecular C9H10BKN6, about Di-μ-azido-bis{[hydrotris(pyrazol-1-yl)borato]copper(II)}, the main research direction is copper azido pyrazolylborato preparation crystal structure; mol structure copper azido pyrazolylborato.Application In Synthesis of Potassiumtris(1-pyrazolyl)borohydride.

Crystals of the title compound are monoclinic, space group P21/n, with a 7.515(1), b 13.363(2), c 13.285(2) Å, β 93.65(1)°; Z = 2, dc = 1.590; R = 0.049, Rw(F2) = 0.110 for 2605 reflections. The mol. is located at a crystallog. inversion center. The two Cu atoms have distorted square-pyramidal coordination and are bridged by two end-on azide groups. Weak C-H···N contacts result in a two-dimensional network with base vectors [101] and [010], parallel to the (101̅) plane.

The article 《Di-μ-azido-bis{[hydrotris(pyrazol-1-yl)borato]copper(II)}》 also mentions many details about this compound(18583-60-3)Application In Synthesis of Potassiumtris(1-pyrazolyl)borohydride, you can pay attention to it, because details determine success or failure

Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

HPLC of Formula: 18583-60-3. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Potassiumtris(1-pyrazolyl)borohydride, is researched, Molecular C9H10BKN6, CAS is 18583-60-3, about Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(I) complexes. Author is Hamze, Rasha; Jazzar, Rodolphe; Soleilhavoup, Michele; Djurovich, Peter I.; Bertrand, Guy; Thompson, Mark E..

The photophys. properties of several Cu(I) complexes coordinated with cyclic (alkyl)(amino)carbene (CAAC) ligands were examined All the compounds were found to be phosphorescent, regardless of whether they are 2-, 3- or 4-coordinated. Aggregate and excimer emission were observed from 2-coordinate CAAC-CuCl derivatives in methylcyclohexane solution Emission from the complex 4-coordinated with a trispyrazolylborate ligand is red-shifted with respect to both the chloro-derivative and an analogous complex with an NHC ligand.

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1-(Bromomethyl)-4-iodobenzene, is researched, Molecular C7H6BrI, CAS is 16004-15-2, about Design and synthesis of cinchona-based chiral hyperbranched polymers and their application in asymmetric reactions, the main research direction is cinchona chiral hyperbranched polymer catalyst preparation diastereoselectivity enantioselectivity addition.Application of 16004-15-2.

Cinchona-based chiral hyperbranched polymers (HBPs) were designed and successfully synthesized via the Mizoroki-Heck (MH) coupling reaction. AB2 and A2B-type chiral monomers were prepared from cinchona squaramide derivatives, where A (vinyl) reacted only with B (iodophenyl) under MH reaction conditions. The chiral HBPs obtained by the MH polymerization contained cinchona squaramide moieties and demonstrated excellent diastereoselectivity and enantioselectivity in asym. Michael addition reactions of Me 2-oxocyclopentanecarboxylate and trans-β-nitrostyrene. These newly designed HBPs were structurally robust and could be reused for further reaction without losing their catalytic activity.

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

HPLC of Formula: 18583-60-3. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Potassiumtris(1-pyrazolyl)borohydride, is researched, Molecular C9H10BKN6, CAS is 18583-60-3, about Organometallic derivatives of actinide polypyrazolylborates. Author is Domingos, A.; Leal, J. P.; Marcalo, J.; Marques, N.; Pires de Matos, A.; Santos, I.; Silva, M.; Kanellakopulos, B.; Maier, R..

A review with 18 references describing the preparation and characterization of actinide compounds containing polypyrazolylborate ligands, e.g., MCl3[HB(3,5-Me2Pz)3](THF) and MCl2(HBPz3)2 (M = Th, U, Np), and of their σ-hydrocarbyl derivatives

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

Application In Synthesis of 1-(Bromomethyl)-4-iodobenzene. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 1-(Bromomethyl)-4-iodobenzene, is researched, Molecular C7H6BrI, CAS is 16004-15-2, about Iodinated Choline Transport-Targeted Tracers.

We present a novel series of radioiodinated tracers and potential theranostics for diseases accompanied by pathol. function of proteins involved in choline transport. Unlike choline analogs labeled with 11C or 18F that are currently used in the clinic, the iodinated compounds described herein are applicable in positron emission tomog., single-photon emission computed tomog., and potentially in therapy, depending on the iodine isotope selection. Moreover, favorable half-lives of iodine isotopes result in much less challenging synthesis by isotope exchange reaction. Six of the described compounds were nanomolar ligands, and the best compound possessed an affinity 100-fold greater than that of choline. Biodistribution data of 125I-labeled ligands in human prostate carcinoma bearing (PC-3) mice revealed two compounds with a biodistribution profile superior to that of [18F]fluorocholine.

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 2-Bromopriopionaldehydediethylacetal, is researched, Molecular C7H15BrO2, CAS is 3400-55-3, about Enol ether-iron complexes as vinyl cation equivalents. Vinylation of enolates, the main research direction is vinyl cation iron enol ether; vinylation stereochem enolate.Quality Control of 2-Bromopriopionaldehydediethylacetal.

The use of Fp(alkyl vinyl ether)+ BF4- complexes as vinyl cation equivalents is described [Fp = C5H5Fe(CO)2]. These salts react with cyclohexanone Li enolate, or its 2- or 6-Me derivatives to give I (R, R1, R2 = H, Me). I are transformed by protonation with HBF4 to the corresponding II, which with I- liberate III. The stereochem. of the alkylation reaction and several other transformations of intermediates are described.

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Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

Willcox, Dominic R.; Nichol, Gary S.; Thomas, Stephen P. published the article 《Borane-Catalyzed C(sp3)-F Bond Arylation and Esterification Enabled by Transborylation》. Keywords: borane boronate catalyst dehydrocoupling aryl fluoride fluoroalkane aromatic hydrocarbon; diarylmethane preparation dehydrocoupling aryl fluoride aromatic hydrocarbon borane catalyst.They researched the compound: 1-(Bromomethyl)-4-iodobenzene( cas:16004-15-2 ).Application In Synthesis of 1-(Bromomethyl)-4-iodobenzene. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:16004-15-2) here.

The activation and functionalization of carbon-fluorine bonds represent a significant synthetic challenge, given the high thermodn. barrier to C-F bond cleavage. Stoichiometric hydridoborane-mediated C-F functionalization has recently emerged, but is yet to be rendered catalytic. Herein, the borane-catalyzed coupling of alkyl fluorides with arenes (carbon-carbon bond formation) and carboxylic acids (carbon-oxygen bond formation) has been developed using transborylation reactions to achieve catalytic turnover. Successful C-C and C-O coupling across a variety of structurally and electronically differentiated arenes and carboxylic acids was achieved using 9-borabicyclo[3.3.1]nonane (H-B-9-BBN) as the catalyst and pinacolborane (HBpin), with broad functional group tolerance. Exptl. and computational studies suggest a mechanistic dichotomy for the carbon-carbon and carbon-oxygen coupling reactions. B-F transborylation (B-F/B-H metathesis) between F-B-9-BBN and HBpin enabled catalytic turnover for carbon-carbon bond formation, whereas direct exchange between the alkyl fluoride and acyloxyboronic ester (C-F/B-O metathesis) was proposed for carbon-oxygen coupling, where H-B-9-BBN catalyzed the dehydrocoupling of the carboxylic acid with HBpin.

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Inorganic Syntheses called Compounds of general interest. Chloro(hydrotris(pyrazol-1-yl)borato)bis(triphenylphosphine)ruthenium(II) {RuCl[κ3-HB(pz)3](PPh3)2} (pz = pyrazol-1-yl), Author is Hill, Anthony F.; Wilton-Ely, James D. E. T.; Rauchfuss, Thomas B.; Schwartz, Daniel E., which mentions a compound: 18583-60-3, SMILESS is [BH-](N1N=CC=C1)(N2N=CC=C2)N3N=CC=C3.[K+], Molecular C9H10BKN6, Safety of Potassiumtris(1-pyrazolyl)borohydride.

RuCl[κ3-HB(pz)3](PPh3)2 complex was synthesized on a large scale (10 g) and was characterized. The procedure is based on the reaction of dichlorotris(triphenylphosphine)ruthenium(II) with hydrotris(pyrazol-1-yl)borate K salt.

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

Electric Literature of C7H6BrI. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 1-(Bromomethyl)-4-iodobenzene, is researched, Molecular C7H6BrI, CAS is 16004-15-2, about Design and synthesis of chiral hyperbranched polymers containing cinchona squaramide moieties and their catalytic activity in the asymmetric Michael addition reaction.

Chiral hyperbranched polymers (HBP) containing cinchona alkaloids were synthesized using a Mizoroki-Heck (MH) coupling polymerization reaction between a cinchona squaramide dimer and tri- or tetra-substituted aromatic iodides. This was a new type of polymeric chiral organocatalyst. We found that the as-obtained chiral HBPs show excellent catalytic activity in the asym. Michael reaction. Almost perfect enantioselectivity (>99% ee) was achieved in the reaction of β-ketoester and trans-β-nitrostyrene. The three-dimensional network structure of the chiral HBPs is structurally robust and can be reused for further reaction without any loss in their catalytic activity.

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Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Calderon, J. L.; Cotton, F. A.; Shaver, Alan researched the compound: Potassiumtris(1-pyrazolyl)borohydride( cas:18583-60-3 ).Electric Literature of C9H10BKN6.They published the article 《Complexes of polypyrazolylborate ligands. II. Conformational isomerism in [hydridotris(1-pyrazolyl)borate] (h5-cyclopentadienyl)dicarbonylmolybdenum and [diethylbis(1-pyrazolyl)borate] (h5-cyclopentadienyl)dicarbonylmolybdenum》 about this compound( cas:18583-60-3 ) in Journal of Organometallic Chemistry. Keywords: pyrazolylborate cyclopentadienyl molybdenum carbonyl; borate cyclopentadienyl molybdenum carbonyl; PMR cyclopentadienylmolybdenum conformation; IR cyclopentadienylmolybdenum conformation. We’ll tell you more about this compound (cas:18583-60-3).

In this abstract C5H5 = h5-cyclopentadienyl. Structural studies of [HB(pz)3](C5H5)(CO)2Mo and [Et2B(pz)2](C5H5)(CO)2Mo, where HB(pz)3 and Et2B(pz)2 represent the hydridotris(pyrazolyl)borate and the diethylbis(pyrazolyl)borate groups, resp., are carried out in solution using ir and PMR spectra. The data indicate that the pyrazolyl groups coordinate as bidentate ligands to form 6-membered rings and that the rings exist in 2 conformations which interconvert in solution, which explains the temperature dependence of the PMR spectrum of [B(pz)4](C5H5)(CO)2Mo.

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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics