Product Details of 53562-86-0. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: (S)-Methyl 3-hydroxybutanoate, is researched, Molecular C5H10O3, CAS is 53562-86-0, about Synthesis of 1,1′-bis(phosphetano)ferrocenes, a new class of chiral ligands for asymmetric catalysis. Author is Marinetti, Angela; Labrue, Francis; Genet, Jean-Pierre.
The C2-sym., chiral 1,1′-bis(phosphetano)ferrocenes I (R = Me, CHMe2) were prepared from the cyclic sulfates of optically pure 1,3-diols. They were successfully tested in the Rh-catalyzed hydrogenation of unsaturated substrates. E.g., hydrogenation of H2C:C(CO2Me)CH2CO2Me in MeOH in presence of a rhodium catalyst formed in situ from (COD)2RhOTf and I (R = Me) gave 100% conversion to (R)-MeCH(CO2Me)CH2CO2Me in 91% ee.
The article 《Synthesis of 1,1′-bis(phosphetano)ferrocenes, a new class of chiral ligands for asymmetric catalysis》 also mentions many details about this compound(53562-86-0)Product Details of 53562-86-0, you can pay attention to it, because details determine success or failure
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics