Zhao, Xue; Li, Xue; Zhang, Haibo; Chen, Xiao; Xu, Jian; Yang, Jun; Zhang, Hucai; Hu, Guangzhi published the article 《Atomic-dispersed copper simultaneously achieve high-efficiency removal and high-value-added conversion to ammonia of nitrate in sewage》. Keywords: copper ammonia nitrate sewage electrocatalytic wastewater treatment; Eliminate NO(3)(-); Nitrate sewage purification; Nitrogen oxides elimination; Single-atom Cu; Sustainable NH(3) synthesis.They researched the compound: 1,10-Phenanthroline( cas:66-71-7 ).SDS of cas: 66-71-7. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:66-71-7) here.
Environmentally friendly electrochem. reduction pathways from NO-3 to NH3 or N2 have provided feasible strategy into the green production of ammonia or the treatment of nitrate wastewater. Here, we anchored single-atom Cu with boron carbon nitride on carbon nanotube (BCN@Cu/CNT), and achieved the efficient operation of electrochem. nitrate reduction reaction (NIRR). BCN@Cu/CNT can efficiently catalyze the selective conversion of high-concentration nitrate into high-value-added ammonia, where the ammonia yield rate and Faradaic efficiency are as high as 172,226.5μg h-1 mg-1cat. and 95.32% (at -0.6 V), resp. BCN@Cu/CNT also shows the ability to efficiently remove low-concentration nitrates in sewage. Specifically, here only takes 5 h to nearly 100% (99.32%) eliminate NO-3 (50 mg L-1) in sewage without any residual NO-2. The excellent catalytic activity and physicochem. stability of BCN@Cu/CNT for NIRR suggest the promising industrial application prospects, including the green production of ammonia and the purification of nitrate wastewater.
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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics