Computed Properties of C9H10BKN6. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Potassiumtris(1-pyrazolyl)borohydride, is researched, Molecular C9H10BKN6, CAS is 18583-60-3, about Tris(pyrazolyl)borate dihydrogen complexes of ruthenium. Author is Halcrow, Malcolm A.; Chaudret, Bruno; Trofimenko, Swiatoslaw.
Reaction of [Ru(PCy3)2(H2)HI] (Cy = cyclohexyl) with K(tpb) [tpb = tris(pyrazol-1-yl)borate(1-)] or Tl(tdmpb) [tdmpb = tris(3,5-dimethylpyrazol-1-yl)borate(1-)] affords [Ru(η3-L)(PCy3)(H2)H] (L = tpb, tdmpb), via the intermediates trans-[Ru(η2-L)(PCy3)2(H2)H]. Protonation of [Ru(tpb)(PCy3)(H2)H] with HBF4.Et2O leads to [Ru(tbp)(PCy3)(OH2)(H2)]BF4.
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