The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Potassiumtris(1-pyrazolyl)borohydride, is researched, Molecular C9H10BKN6, CAS is 18583-60-3, about Synthesis and Reactivity of [TpRh(PPh3)2] (Tp = Hydridotris(pyrazol-1-yl)borate), the main research direction is rhodium hydridotris pyrazolylborate phosphine preparation reactivity; crystal structure hydridotrispyrazolylborate rhodium phosphine complex; mol structure hydridotrispyrazolylborate rhodium phosphine complex.Product Details of 18583-60-3.
The new complex [TpRh(PPh3)2] (I), readily obtained from [RhCl(PPh3)3] and KTp, is a particularly convenient and versatile entry point into the organometallic chem. of the “”TpRh”” fragment including complexes bearing alkyne, alkene, carbene, thiocarbamoyl, dithioalkoxycarbonyl, carbon disulfide, and vinyl ligands. Thus, reaction of I with di-Me acetylenedicarboxylate, N,N-dimethylthiocarbamoyl chloride, or carbon disulfide followed by chloroform chlorination gave [TpRh{η2-C2(CO2Me)2}(PPh3)], [TpRh(η2-SCNMe2)(PPh3)]Cl, and [TpRh{:C(SMe)2}Cl2] resp. which were characterized by x-ray crystal structure determination
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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics