Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , SDS of cas: 16153-81-4, 16153-81-4, Name is 4-(4-Methylpiperazin-1-yl)phenylamine, molecular formula is C11H17N3, belongs to piperazines compound. In a document, author is Zahradnikova, Eva, introduce the new discover.
Late first-row transition metal complexes of a 17-membered piperazine-based macrocyclic ligand: structures and magnetism
A 17-membered piperazine-based macrocyclic ligandL(diProp)(1,5,13,17,22-pentaazatricyclo[15.2.2.17,11]docosa-7,9,11(22)-triene) was resynthesized in high yield by using a linear pump. Its Mn(ii), Fe(ii), Co(ii) and Ni(ii) complexes of the general formula [MnLdiProp(ClO4)(2)] (1), [FeLdiProp(CH3CN)](ClO4)(2)(2), [CoLdiProp(CH3CN)](ClO4)(2)(3), [NiLdiProp](ClO4)(2)(4) were prepared and thoroughly characterized. X-ray diffraction analysis confirmed that Mn(ii) complex1has capped trigonal prismatic geometry with a coordination number of seven, Fe(ii) and Co(ii) complexes2and3are trigonal prismatic with a coordination number of six and Ni(ii) complex4has square pyramidal geometry with a coordination number of five. The decrease of the coordination number is accompanied by a shortening of M-N distances and an increase of torsion of the piperazine ring from the equatorial plane. Magnetic measurement reveals moderate anisotropy for4and rather large magnetic anisotropy for2and3(axial zero-field splitting parameterD(Ni) = 9.0 cm(-1),D(Fe) = -14.4 cm(-1),D(Co) = -25.8 cm(-1), together with rather high rhombicity). Co(ii) complex3behaves as a field-induced SMM with a combination of Raman and direct or Orbach and direct relaxation mechanisms. Obtained magnetic data were extensively supported by theoretical CASSCF calculations. The flexibility and rather large 17-membered macrocyclic cavity of ligandL(diProp)could be responsible for the variation of coordination numbers and geometries for the investigated late-first row transition metals.
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Reference:
Piperazine – Wikipedia,
,Piperazines – an overview | ScienceDirect Topics