Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 18583-60-3, is researched, SMILESS is [BH-](N1N=CC=C1)(N2N=CC=C2)N3N=CC=C3.[K+], Molecular C9H10BKN6Journal, Organometallics called Polyazolyl Chelate Chemistry. 6. Bidentate Coordination of HB(pz)3 (pz = Pyrazol-1-yl) to Ruthenium and Osmium: Crystal Structure of [RuH(CO)(PPh3)2{κ2-HB(pz)3}], Author is Burns, Ian D.; Hill, Anthony F.; White, Andrew J. P.; Williams, David J.; Wilton-Ely, James D. E. T., the main research direction is crystal structure trispyrazolylborato hydrido bisphosphine ruthenium; mol structure trispyrazolylborato hydrido ruthenium bisphosphine; ruthenium trispyrazolylborato hydrido preparation structure metathesis; pyrazolylborato ruthenium hydrido preparation structure metathesis; polyazolylborato ruthenium hydrido preparation structure metathesis; osmium polyazolylborato hydrido preparation; thiocarbonyl polyazolylborato osmium ruthenium preparation.Related Products of 18583-60-3.
The reactions of [RuHCl(CO)(PPh3)3], [Ru(SnPh3)Cl(CO)(PPh3)2], or [RuH(CO)(NCMe)2(PPh3)2]BF4 with K[HB(pz)3] (pz = pyrazol-1-yl) provide the crystallog. characterized complex [RuH(CO)(PPh3)2{η2-HB(pz)3}], thermolysis of which proceeds via loss of phosphine and formation of [RuH(CO)(PPh3){η3-HB(pz)3}]. The thiocarbonyl analog [RuH(CS)(PPh3)2{η2-HB(pz)3}] is similarly obtained by the reaction of [RuHCl(CS)(PPh3)3] and K[HB(pz)3], thermolysis of which provides [RuH(CS)(PPh3){η3-HB(pz)3}]. Hydride metathesis in CHCl3 of this species provides [RuCl(CS)(PPh3){η3-HB(pz)3}]. [RuH(CS)(PPh3)2{η2-H2B(bta)2}] (bta = benzotriazolyl) results from the reaction of [RuHCl(CS)(PPh3)3] with K[H2B(bta)2]. The hydride-bridged dinuclear complex [RuCu(μ-H)(CO)(PPh3)2{η3-HB(pz)3}]PF6 results in high yield from the reaction of [RuH(CO)(PPh3)2{η2-HB(pz)3}], with [Cu(NCMe)4]BF4. The σ-Ph complex [OsPh(CO)(PPh3)2{η2-HB(pz)3}] results from the reaction of [OsPhCl(CO)(PPh3)2] with K[HB(pz)3] and is cleanly converted with heating to [OsPh(CO)(PPh3){η3-HB(pz)3}].
After consulting a lot of data, we found that this compound(18583-60-3)Related Products of 18583-60-3 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics