The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1,10-Phenanthroline, is researched, Molecular C12H8N2, CAS is 66-71-7, about Phenanthroline bridging graphitic carbon nitride framework and Fe (II) ions to promote transfer of photogenerated electrons for selective photocatalytic reduction of Nitrophenols, the main research direction is phenanthroline graphitic carbon nitride nitrophenol photocatalytic reduction; Fe (II); Graphitic carbon nitride; Nitrophenols; Phenanthroline; Selective reduction.Formula: C12H8N2.
Nitrophenols (NPs) are widely used in industries and highly toxic to ecol. environment and human health. Because aminophenols (APs) are important chems., catalytic reduction of NPs via efficient and environment-friendly strategies is of great importance. Herein, we developed a green photocatalysis route to efficiently convert NPs to APs using a Fe (II) modified graphitic carbon nitride (g-C3N4) photocatalyst, where phenanthroline units were employed to bridge Fe (II) and carbon nitride framework. The optimized sample P-CN-8-Fe presented significantly improved absorption of visible light, separation of photogenerated charges and carrier transportation in comparison with the pristine g-C3N4 and the modified samples of CN-Fe and P-CN-8. Accordingly, the P-CN-8-Fe showed a high conversion (97%) of p-nitrophenol (p-NP) to p-aminophenol (p-AP) under 2 h visible light irradiation, and meanwhile possessed high photocatalytic durability. Its high activity was also demonstrated through photocatalytic reduction of other NPs and nitrobenzene compounds Finally, a possible mechanism was proposed for the photocatalytic reduction of p-NP by P-CN-8-Fe. This work provides an effective approach to prepare Fe (II) modified g-C3N4 through the bridging effect of phenanthroline group, which is a potential visible light driven photocatalyst for reduction of nitrobenzene derivatives
As far as I know, this compound(66-71-7)Formula: C12H8N2 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics