The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Potassiumtris(1-pyrazolyl)borohydride, is researched, Molecular C9H10BKN6, CAS is 18583-60-3, about Enantiocontrolled [5 + 2] Cycloaddition to η3-Pyranylmolybdenum π-Complexes. Synthesis of Substituted Oxabicyclo[3.2.1]octenes of High Enantiopurity, the main research direction is crystal structure oxabicyclooctene molybdenum oxabicyclooctenyl complex; mol structure oxabicyclooctene molybdenum oxabicyclooctenyl complex; enantiocontrolled cycloaddition alkene pyranyl molybdenum pi complex; oxabicyclooctene stereoselective synthesis; demetalation molybdenum oxabicyclooctenyl complex.Category: piperazines.
A novel molybdenum-mediated [5 + 2] cycloaddition reaction is reported. The reactions proceed in good to excellent yields and give products with high enantiomeric excesses, complete regioselectivities, and moderate to excellent exo/endo selectivities. A stepwise mechanism for the cycloaddition reaction was established, and three general demetalation protocols (protodemetalation, iododemetalation, oxidative demetalation) were developed to furnish a large variety of substituted oxabicyclo[3.2.1]octene rings. The crystal and mol. structures of I and II were determined by x-ray crystallog.
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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics