In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Nucleophilic and Radical Heptafluoroisopropoxylation with Redox-Active Reagents, published in 2021-10-11, which mentions a compound: 16004-15-2, mainly applied to heptafluoroisopropyl ether preparation; hydroxylamine oxidative heptafluoroisopropyl silver heptafluoroisopropylation; conformation; heptafluoroisopropoxylation; nucleophilic reactions; radical reactions; redox-active reagents, Electric Literature of C7H6BrI.
The practical and efficient heptafluoroisopropoxylation reactions through the invention of a series of redox-active N-OCF(CF3)2 reagents e.g., I were described. These reagents were readily prepared from the oxidative heptafluoroisopropylation of hydroxylamines e.g., II with AgCF(CF3)2. The substitutions on the nitrogen atom significantly affected the properties and reactivities of N-OCF(CF3)2 reagents. Accordingly, two types of N-OCF(CF3)2 reagents including I and III were used as OCF(CF3)2 anion and radical precursors, resp. This protocol enables the direct heptafluoroisopropoxylation of a range of substrates, delivering the corresponding products in moderate to excellent yields.
If you want to learn more about this compound(1-(Bromomethyl)-4-iodobenzene)Electric Literature of C7H6BrI, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(16004-15-2).
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics