Safety of 1-(Bromomethyl)-4-iodobenzene. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 1-(Bromomethyl)-4-iodobenzene, is researched, Molecular C7H6BrI, CAS is 16004-15-2, about Chemo-, regio- and stereoselective synthesis of monofluoroalkenes via a tandem fluorination-desulfonation sequence. Author is Yang, Ren-Yin; Xu, Bo.
A widely applicable approach for the synthesis of Z-monofluoroalkenes ArC(F):CHR [R = Ph, 2-naphthyl, 3-BrC6H4, etc., Ar = Ph, 4-NCC6H4, 4-O2NC6H4, etc.] from readily available alkyl triflones and NFSI was reported. The reaction proceeded under mild conditions, affording the mono-fluorinated alkenes in good to excellent yields with excellent chemo-, regio-, and stereoselectivity. The mechanism might involve electrophilic fluorination of triflones followed by the highly stereoselective concerted bimol. elimination (E2) of CF3SO2H.
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